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Has already been reported and fixed for some time, please ignore the check and wait until the next release. https://github.com/kwsch/PKHeX/commit/0b5116f5677d244fc4de9ebb68cfd1cfc46d7dd1

To fix it you need to generate a PID/IV with Gender Female (12.5%) using RNG Reporter. Most likely it will change the Nature and/or IVs. I can tell yours is hacked cause of IVs (31-31-31-24-31-31) almost impossible. Anyway, here's a "fixed" file. 416 - Vespiquen - 27AAC27D781A.pk7

I see.......once again,Thank you very much for your help

Given it's all yes, it is possible that your account for your PC don't have permissions to use PKHeX to write into the Citra folder. (I'm surprised that loading PKHeX as Administrator didn't solve that problem) Which is also why the error regarding "System.UnauthorizedAccessException: Access to the path 'D:\User\Documents\Citra 3DS\PKHeX\bak\main [May (OR) - 2020-03-06 15ː46].bak' is denied." occurred as well. Thus from this point onward, you gotta edit the main somewhere else, then copy it manually to overwrite the save in the Citra folder.

1. Can you copy the main from the citra folder to your desktop? (nothing to do with PKHeX) 2. can you then use PKHeX to edit the save on your desktop? 3. Can you then use PKHeX to save over and overwrite the save on your desktop? 4. Can you copy the save from your Desktop and overwrite the save in the Citra folder? (nothing to do with PKHeX) Note: this is what is looks like to save the progress of your save editing. It's the export sav and export main option.

The version of the file doesn't matter to PKHeX. PKHeX is just a save editor. It doesn't have feelings nor does it care. Use whatever file you like (that's compatible with PKHeX). PKHeX doesn't tell you what stage of the story you're at. You gotta load the save in the game in order be able to tell. You can edit progression by checking or unchecking event flags, but the flags aren't labelled. It is probably just easier to import all the mons into a save of yours, as you already know the story progression of your own save.

the way I see it, not the files problem. PK6 is a format for .pkm in generation 6, nothing wrong with it. I think you don't have rights to save in that location. Are you able to export save or save Pokemon in any other directory? Are you able to run as administrator? Also, please answer all above questions. AND, stop multiposting. I merged your posts.

try to save a mon on the desktop instead? Maybe you need PKHeX to be opened as Administrator to save into that folder.

Can you try opening a save that you download from the internet, as opposed to any save from Citra? Also, maybe remove this and try again (on your Citra save), and see if it helps

seems to open fine on my PKHeX. Can you PKHeX open any other save?

the main file.

upload your save here, I'll see if it boots

and have you at last picked a starter in the game already?

Let's answer the first part first. Your game on CITRA isn't running while you're trying to open the file, right?

Are you sure the save has been initialized, that there's save data. Is this file a backup? Is PKHeX trying to access a backup? Does the file exist?

@javisoto99it appears to be an error with the current version of PKHeX. I was able to replicate the issue multiple times with Ralts that I hatched in the Battle Frontier. For some reason PKHeX is detecting that the Battle Frontier is a Platinum only location and if the egg met conditions is changed to Link Trade (Egg) it will turn legal.

By chance could you upload the file here? It'll make it easier to determine the issue.

PID gender would have been encountered as a Male Combee, which can't evolve to Vespiquen. PKHeX is working as intended, flagging this as hacked is correct.

last warning, stop multi-posting. Anything to add, edit into your latest unanswered post. Also, when you answer me later, make sure you follow the 4 points and answer in point form.